{"id":12440,"date":"2024-08-25T11:35:48","date_gmt":"2024-08-25T11:35:48","guid":{"rendered":"https:\/\/topat10.com\/?p=12440"},"modified":"2024-08-25T11:35:48","modified_gmt":"2024-08-25T11:35:48","slug":"the-quantum-mechanics-of-the-greenhouse-effect","status":"publish","type":"post","link":"https:\/\/topat10.com\/?p=12440","title":{"rendered":"The Quantum Mechanics of the Greenhouse Effect"},"content":{"rendered":"<p> <br \/>\n<\/p>\n<div>\n<p class=\"paywall\">A key question was the origin of the logarithmic scaling of the greenhouse effect\u2014the 2-to-5-degree temperature rise that models predict will happen for every doubling of CO<sub>2<\/sub>. One theory held that the scaling comes from how quickly the temperature drops with altitude. But in 2022, a team of researchers used a simple model to prove that the logarithmic scaling comes from the shape of carbon dioxide\u2019s absorption \u201cspectrum\u201d\u2014how its ability to absorb light varies with the light\u2019s wavelength.<\/p>\n<p class=\"paywall\">This goes back to those wavelengths that are slightly longer or shorter than 15 microns. A critical detail is that carbon dioxide is worse\u2014but not too much worse\u2014at absorbing light with those wavelengths. The absorption falls off on either side of the peak at just the right rate to give rise to the logarithmic scaling.<\/p>\n<p class=\"paywall\">\u201cThe shape of that spectrum is essential,\u201d said <a href=\"https:\/\/eps.berkeley.edu\/people\/david-romps\" target=\"_blank\" rel=\"noopener\">David Romps<\/a>, a climate physicist at the University of California, Berkeley, who coauthored the 2022 paper. \u201cIf you change it, you don\u2019t get the logarithmic scaling.\u201d<\/p>\n<p class=\"paywall\">The carbon spectrum\u2019s shape is unusual\u2014most gases absorb a much narrower range of wavelengths. \u201cThe question I had at the back of my mind was: Why does it have this shape?\u201d Romps said. \u201cBut I couldn\u2019t put my finger on it.\u201d<\/p>\n<h2 class=\"paywall\">Consequential Wiggles<\/h2>\n<p class=\"paywall\">Wordsworth and his coauthors Jacob Seeley and Keith Shine turned to quantum mechanics to find the answer.<\/p>\n<p class=\"paywall\">Light is made of packets of energy called photons. Molecules like CO<sub>2<\/sub> can absorb them only when the packets have exactly the right amount of energy to bump the molecule up to a different quantum mechanical state.<\/p>\n<p class=\"paywall\">Carbon dioxide usually sits in its \u201cground state,\u201d where its three atoms form a line with the carbon atom in the center, equidistant from the others. The molecule has \u201cexcited\u201d states as well, in which its atoms undulate or swing about.<\/p>\n<div class=\"GenericCalloutWrapper-tojWn gEhPRA callout--has-top-border\" data-testid=\"GenericCallout\">\n<figure class=\"AssetEmbedWrapper-eVDQiB byBkf asset-embed\">\n<div class=\"AssetEmbedAssetContainer-eJxoAx dBHGoQ asset-embed__asset-container\"><span class=\"SpanWrapper-umhxW kGxnNB responsive-asset AssetEmbedResponsiveAsset-cXBNxi eCxVQK asset-embed__responsive-asset\"><picture class=\"ResponsiveImagePicture-cWuUZO dUOtEa AssetEmbedResponsiveAsset-cXBNxi eCxVQK asset-embed__responsive-asset responsive-image\"><noscript><img decoding=\"async\" alt=\"Image may contain Sphere Egg Food and Balloon\" class=\"ResponsiveImageContainer-eybHBd fptoWY responsive-image__image lazyload\" src=\"data:image\/gif;base64,R0lGODlhAQABAAAAACH5BAEKAAEALAAAAAABAAEAAAICTAEAOw==\" data-src=\"https:\/\/media.wired.com\/photos\/66c36cfb3b109b0e1cb99d5e\/master\/w_1600%2Cc_limit\/GreenhouseEffect-Spots-Co2-Spot-02-1523x1720.jpeg\" data-sizes=\"auto\" data-srcset=\"https:\/\/media.wired.com\/photos\/66c36cfb3b109b0e1cb99d5e\/master\/w_120,c_limit\/GreenhouseEffect-Spots-Co2-Spot-02-1523x1720.jpeg 120w, https:\/\/media.wired.com\/photos\/66c36cfb3b109b0e1cb99d5e\/master\/w_240,c_limit\/GreenhouseEffect-Spots-Co2-Spot-02-1523x1720.jpeg 240w, https:\/\/media.wired.com\/photos\/66c36cfb3b109b0e1cb99d5e\/master\/w_320,c_limit\/GreenhouseEffect-Spots-Co2-Spot-02-1523x1720.jpeg 320w, https:\/\/media.wired.com\/photos\/66c36cfb3b109b0e1cb99d5e\/master\/w_640,c_limit\/GreenhouseEffect-Spots-Co2-Spot-02-1523x1720.jpeg 640w, https:\/\/media.wired.com\/photos\/66c36cfb3b109b0e1cb99d5e\/master\/w_960,c_limit\/GreenhouseEffect-Spots-Co2-Spot-02-1523x1720.jpeg 960w, https:\/\/media.wired.com\/photos\/66c36cfb3b109b0e1cb99d5e\/master\/w_1280,c_limit\/GreenhouseEffect-Spots-Co2-Spot-02-1523x1720.jpeg 1280w, https:\/\/media.wired.com\/photos\/66c36cfb3b109b0e1cb99d5e\/master\/w_1600,c_limit\/GreenhouseEffect-Spots-Co2-Spot-02-1523x1720.jpeg 1600w\" sizes=\"100vw\"\/><\/noscript><\/picture><\/span><\/div>\n<\/figure>\n<\/div>\n<p class=\"paywall\">A photon of 15-micron light contains the exact energy required to set the carbon atom swirling about the center point in a sort of hula-hoop motion. Climate scientists have long blamed this hula-hoop state for the greenhouse effect, but\u2014as \u00c5ngstr\u00f6m anticipated\u2014the effect requires too precise an amount of energy, Wordsworth and his team found. The hula-hoop state can\u2019t explain the relatively slow decline in the absorption rate for photons further from 15 microns, so it can\u2019t explain climate change by itself.<\/p>\n<p class=\"paywall\">The key, they found, is another type of motion, where the two oxygen atoms repeatedly bob toward and away from the carbon center, as if stretching and compressing a spring connecting them. This motion takes too much energy to be induced by Earth\u2019s infrared photons on their own.<\/p>\n<p class=\"paywall\">But the authors found that the energy of the stretching motion is so close to double that of the hula-hoop motion that the two states of motion mix with one another. Special combinations of the two motions exist, requiring slightly more or less than the exact energy of the hula-hoop motion.<\/p>\n<p class=\"paywall\">This unique phenomenon is called Fermi resonance after the famous physicist Enrico Fermi, who derived it in a 1931 paper. But its connection to Earth\u2019s climate was only made for the first time in <a href=\"https:\/\/ui.adsabs.harvard.edu\/abs\/2023QJRMS.149.1856S\/abstract\" target=\"_blank\" rel=\"noopener\">a paper<\/a> last year by Shine and his student, and the paper this spring is the first to fully lay it bare.<\/p>\n<\/div>\n\n","protected":false},"excerpt":{"rendered":"<p>A key question was the origin of the logarithmic scaling of the greenhouse effect\u2014the 2-to-5-degree temperature rise that models predict will happen for every doubling of CO2. One theory held that the scaling comes from how quickly the temperature drops with altitude. But in 2022, a team of researchers used a simple model to prove [&hellip;]<\/p>\n","protected":false},"author":568,"featured_media":12441,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"_uag_custom_page_level_css":"","_jetpack_memberships_contains_paid_content":false,"footnotes":""},"categories":[703],"tags":[894,1097,914,2588,890],"class_list":["post-12440","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-technology","tag-climate-change","tag-environment","tag-quanta-magazine","tag-quantum-physics","tag-science"],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v27.4 - https:\/\/yoast.com\/product\/yoast-seo-wordpress\/ -->\n<title>The Quantum Mechanics of the Greenhouse Effect | Unlock Informed Choices with Us<\/title>\n<meta name=\"description\" content=\"Carbon dioxide\u2019s powerful heat-trapping effect has been traced to a quirk of its quantum structure. 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Howlett","author_link":"https:\/\/topat10.com\/?author=568"},"uagb_comment_info":0,"uagb_excerpt":"A key question was the origin of the logarithmic scaling of the greenhouse effect\u2014the 2-to-5-degree temperature rise that models predict will happen for every doubling of CO2. One theory held that the scaling comes from how quickly the temperature drops with altitude. But in 2022, a team of researchers used a simple model to prove&hellip;","jetpack_sharing_enabled":true,"_links":{"self":[{"href":"https:\/\/topat10.com\/index.php?rest_route=\/wp\/v2\/posts\/12440","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/topat10.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/topat10.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/topat10.com\/index.php?rest_route=\/wp\/v2\/users\/568"}],"replies":[{"embeddable":true,"href":"https:\/\/topat10.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=12440"}],"version-history":[{"count":0,"href":"https:\/\/topat10.com\/index.php?rest_route=\/wp\/v2\/posts\/12440\/revisions"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/topat10.com\/index.php?rest_route=\/wp\/v2\/media\/12441"}],"wp:attachment":[{"href":"https:\/\/topat10.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=12440"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/topat10.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=12440"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/topat10.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=12440"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}